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Title: Synthetic approaches to medium rings
Author: Lawson, Alexander Macnair
Awarding Body: University of Glasgow
Current Institution: University of Glasgow
Date of Award: 1966
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Synthetic routes to 10-membered carbocycles via doubly-bridged tricyclic precursors have been investigated. Starting from dimedone, diethylsuccinylsuccinate and 2-phenylbicyclo-(3;3;1)-nonane-3,9-dione, several novel compounds and complex rearrangements were encountered but no tricyclic compounds were formed. In the course of these studies it was noted that non-enolisable beta-diketones give rise to a characteristic v(C=0) doublet in the infra-red of Deltav(C=0) ca. 30 cm.-1.
Supervisor: Not available Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available