Use this URL to cite or link to this record in EThOS: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.791083 |
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Title: | Plasma device for carbon dioxide conversion and utilisation | ||||||
Author: | Randi, Adriano |
ISNI:
0000 0004 8500 769X
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Awarding Body: | Loughborough University | ||||||
Current Institution: | Loughborough University | ||||||
Date of Award: | 2019 | ||||||
Availability of Full Text: |
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Abstract: | |||||||
The increasing levels of CO2 in the atmosphere and its consequential impact on global warming is driving many research groups to develop ways to use CO2 as raw material. For example, to produce feedstocks, or fuels. A wide variety of approaches to carbon dioxide utilisation have been reported employing homogeneous catalysis, heterogeneous catalysis, photocatalysis, photoreduction and electrochemical reduction. Besides the reduction of greenhouse gases, by producing feedstocks using CO2 will greatly reduce our dependence of fossil fuels for chemical synthesis. Our previously reported electrochemical processes have proven to be successful in terms of electron transfer between substances at room temperature and atmospheric pressure. Atmospheric-pressure plasmas interacting with organic liquids offer a new possibility for chemical synthesis that remains largely unexplored. Here I reported the results obtained with a Jet device in which chemical reactions are triggered in an organic liquid by an atmospheric-pressure plasma. As a proof-of-concept, I considered the incorporation of CO2 into an alkyne to form a carboxylic acid. Here I explore plasma reduction. A CO2 saturated solution of trans-stilbene in Lithium Tetrafluoroborate (LiBF4), and Dimethylformamide (DMF). Argon DC plasma is used as a gaseous cathode to provide electrons for the reduction of CO2. Gas chromatography Mass Spectroscopy (GCMS) and Nuclear Magnetic Resonance (NMR) analysis indicate the formation of its corresponding carboxylic acid with good selectivity.
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Supervisor: | Not available | Sponsor: | Not available | ||||
Qualification Name: | Thesis (Ph.D.) | Qualification Level: | Doctoral | ||||
EThOS ID: | uk.bl.ethos.791083 | DOI: | |||||
Keywords: | electrochemistry ; Atmospheric Pressure Plasma ; CO2 ; carbon dioxide utilisation ; CO2 reduction ; Carboxylic Acid Synthesis | ||||||
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