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Title: A study of some quinoxaline and halo-pyridine complexes of transition metals
Author: Billing, David E.
Awarding Body: Loughborough University of Technology
Current Institution: Loughborough University
Date of Award: 1967
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The preparations and properties of fifty-three new complexes of Cobalt (II), Nickel (II), Copper (II) and Copper (I) halides and nitrates are described. The ligands used were 3-Bromopyridine, 4-Chloropyridine, 1:2:4-Triazole, Quinoxaline, 2-Methylquinoxaline, 2:3-Dimethylquinoxaline, 2:3-Diphenylquinoxaline and Phenazine. The electronic reflectance spectra of these complexes have been measured, and the spin-allowed transitions assigned. The calculated ligand-field parameters are compared with those of related complexes, and the value of such calculations assessed. The spectra, along with confirmatory magnetic and infrared data are used to elucidate the stereochemistries of the complexes.
Supervisor: Not available Sponsor: Loughborough University of Technology
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: Chemical Sciences not elsewhere classified