Use this URL to cite or link to this record in EThOS:
Title: Graphene optical and microwave molecular sensing platforms
Author: Black, Nicola Charlotte
ISNI:       0000 0004 7969 8981
Awarding Body: Imperial College London
Current Institution: Imperial College London
Date of Award: 2019
Availability of Full Text:
Access from EThOS:
Access from Institution:
The unique electronic and physical structure of graphene is highly sensitive to its surroundings, producing a promising candidate for future sensor technologies. However, graphene responds equally to perturbations at both sides of its interface, such that tuning the chemical potential of the substrate at the graphene-solid interface impacts the sensor response at the graphene-gas/liquid interface. In this work, two distinct non-contact graphene sensing platforms are studied under various ambient conditions to assess their propensity towards molecular sensing. The different spectral enhancement mechanisms of graphene surface enhanced Raman spectroscopy platforms are studied through interfacing graphene to differently treated gold nanodisc substrates. Using statistical Raman analysis, the influence of the chemical enhancement mechanism with respect to the graphene Raman peaks is assessed. Moreover, Kelvin force microscopy shows that the locally enhanced electromagnetic field can induce surface chemical reactions which are dependent upon the sensor environment. Explicitly, laser illumination in an air/nitrogen ambient, p-/n-dopes the graphene sheet by -0.87 0.05 meV/ +0.75 0.07 meV. By measuring the change of resistivity of graphene upon gas adsorption using a microwave dielectric resonator, a contactless non-invasive gas sensing platform is demonstrated. This large area graphene measurement platform allows evaluation of the real time sorption processes of NO2 with graphene. Using a modified Langmuir adsorption model, the sticking coefficient is exponentially dependent upon NO2 occupancy. Consequently, the possible variation of the NO2 binding energy, which is frequently considered as the main parameter, plays only a secondary role compared to the rising adsorption energy barrier with increasing NO2 coverage. Finally, through preliminary temperature and electrical gating measurements the charge transfer affinity of graphene based NO2 sensors is explored. Interestingly, the sensor response can be hindered and/or enhanced by back gate control of the doping in graphene.
Supervisor: Cohen, Lesley ; Maier, Stefan Sponsor: Engineering and Physical Sciences Research Council
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral