Use this URL to cite or link to this record in EThOS: https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.773361
Title: An isotopic study of the chemical evolution of groundwater in the peridotite aquifers of the Oman-United Arab Emirates ophiolite
Author: Bompard, Nicolas
ISNI:       0000 0004 7960 7744
Awarding Body: University of Southampton
Current Institution: University of Southampton
Date of Award: 2019
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Abstract:
The low-temperature alteration of peridotite in ophiolites produces two types of fluids, Mg-HCO3- rich, pH < 10 water (Type I) in the shallow subsurface, and Ca-OH- rich, pH >10 water (Type II) deeper in the aquifer, through a combination of serpentinisation and carbonation reactions. Upon discharge, the Type II waters reacts with environmental CO2 and precipitate massive carbonate terraces, potentially providing a powerful means to mitigate the climate change resulting from human-induced high levels of atmospheric CO2. The impact of such carbonate precipitation on the global carbon cycle depends on the rock source of the calcium. Carbonate precipitation with Ca2+ derived from the dissolution of carbonate minerals has no net effect on atmospheric CO2, whereas Ca2+ from the dissolution of silicate phases will contribute to a net drawdown. However, the water-rock reactions responsible for the evolution of the groundwater in peridotite aquifers and the mineral phases involved are still poorly understood. In this study, the changes in ion concentrations, 87Sr/86Sr, 44/40Ca and 88Sr in water along the flow paths and the isotopic composition of a selection of rocks and secondary minerals from the Oman-United Arab Emirates ophiolite are used to investigate the water-rock reactions occurring in the ophiolite subsurface. The data reveal that multiple processes are responsible for the observed evolution of Type I and II waters: (1) Dissolution of secondary minerals, such as serpentine and brucite, which have extensively replaced peridotite primary minerals during previous alteration episodes, play an important role in the modern water-rock interactions and in the water chemistry evolution in the peridotite aquifer; (2) Dolomite precipitation affects the dissolved Ca and Mg concentrations in Type I water; and (3) Ca2+ remobilisation associated with Mg2+ exchange during dolomitisation is the main source of Ca2+ in Type II water, preventing any CO2 release from the carbonates by binding the CO32- ions with Mg2+. The original source of Mg2+ from serpentine alteration and the subsurface exchange during dolomitisation ensures that the precipitation of carbonates in hyperalkaline springs is a sink in the global carbon cycle, and indicates that engineered peridotite alteration could be useful as a climate change mitigation strategy.
Supervisor: Matter, Juerg Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.773361  DOI: Not available
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