Use this URL to cite or link to this record in EThOS: https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.763353
Title: The effect of para-substitution on properties of the N-H bond in anilines
Author: Vallance, Victor
Awarding Body: Loughborough University of Technology
Current Institution: Loughborough University
Date of Award: 1969
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Abstract:
The effects of p-substitution on certain properties of the N-H bond in aniline have been examined in this experimental study. The dipole moments and NH group stretching frequencies of aniline, p-anisidine, p-toluidine, p-chloroaniline, p-bromoaniline and p-cyanoaniline have been determined in cyclohexane and dioxan and the affinity of these compounds for dioxan in solution, and for an activated alumina adsorbent at the solution-solid interface assessed. Dipole moments have been calculated from measurements of dielectric constant, refractive index and density of a series of solutions of graded concentration. The affinity of the anilines for dioxan have been determined from measurements of optical density in the ultra-violet region of the spectrum.
Supervisor: Not available Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.763353  DOI: Not available
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