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Title: Crystal structures of some compounds containing phosphorus-sulphur bonds
Author: Goodacre, G. W.
Awarding Body: Loughborough University of Technology
Current Institution: Loughborough University
Date of Award: 1970
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There is conflicting NMR and spectroscopic evidence in the literature for the molecular structure of diphosphine disulphides. Bis(cyclotetramethylene) diphosphine disulphide and bis(cyclopentamethylene) diphosphine disulphide have been investigated by three-dimensional single crystal X-ray techniques to determine their structure, to obtain accurate values for P–P and P→S bond lengths, and to observe any special features resulting from the inclusion of phosphorus in heterocyclic rings. A rough structure of tetramethyl diphosphine disulphide had previously been published based on vary limited two-dimensional data, and this structure has been confirmed and refined from three-dimensional data.
Supervisor: Not available Sponsor: Science Research Council
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available