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Title: Studies in aryne chemistry
Author: Jablonski, John M.
Awarding Body: Loughborough University of Technology
Current Institution: Loughborough University
Date of Award: 1968
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The principal methods for the generation of arynes and the types of reactions which they undergo are briefly reviewed. Tetrachlorobenzyne has been generated from pentachlorophenyl magnesium chloride, pentachlorophenyl lithium, and tetrachloroanthranilic acid. Reactions of tetrachlorobenzyne with benzene, substituted benzenes, naphthalene, anthracene, furan, tetraphenylcyclopentadienone, 1,3-diphenyl-isobenzofuran, crotonaldehyde and acrolein are reported. Cycloadducts are obtained from those reactions in good yield. Certain reactions of tetrachlor-4-pyridyl lithium are reported.
Supervisor: Not available Sponsor: Loughborough University of Technology
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available