Use this URL to cite or link to this record in EThOS: https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.753093
Title: Extraction and modification of lignin to support enhanced utilisation using critical fluids
Author: Hamzah, Muhammad Hazwan Bin
ISNI:       0000 0004 7426 2003
Awarding Body: University of Birmingham
Current Institution: University of Birmingham
Date of Award: 2018
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Abstract:
Lignin is abundant naturally occurring biopolymer currently produced as a by-product from the pulping and paper industry, where the process generates lignin in the form of lignosulphonates. While there are many applications for lignin there are all low value and attempts to add value to lignin are hindered by its complex physico-chemical nature and the presence of sulphur. Adopting the biorefining concept the study evaluates the impact of direct (DE) and sequential extraction (SE) of Miscanthus x giganteus using sub-critical water with associated modifiers on the physical and chemical properties of the extracted lignin. Even though higher delignification was achieved by DE (81.5%) than SE (58.0%), the lignin recovered from the SE process showed significantly higher purity (91.5%). Fourier Transform Infrared Spectroscopy (FTIR) analysis also revealed the abundance of free hydroxyl groups (OH) within the lignin derived from SE. Further it was demonstrated that lignin agglomerates, which are widely known to form post extraction, could be de-agglomerated by simply reducing the ethanol concentration from 50% to 1% and therefore intramolecular forces. Although the finding does not offer an adequate explanation regards to the driving forces of lignin aggregates at different ethanol concentration, the esterification reaction to attach C12 fatty acids to lignin derived from SE at 50% ethanol concentration (5 mg/mL) demonstrated that the amount of hydroxyl groups available increased the level of fatty acid incorporated onto the lignin macromolecule with 81.2% esterification conversion. A modified lignin produced has the potential to be used as a precursor for added value bio-based materials.
Supervisor: Not available Sponsor: Ministry of Higher Education Malaysia ; Universiti Putra Malaysia
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.753093  DOI: Not available
Keywords: TP Chemical technology
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