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Title: Investigation into the mode of action of chloride and chloridoplatinate extraction : a computational and experimental study
Author: MacRuary, Kirstian Jennifer
ISNI:       0000 0004 6500 2875
Awarding Body: University of Edinburgh
Current Institution: University of Edinburgh
Date of Award: 2017
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This thesis investigates the mode of action of cationic reagents in the recovery of platinum group metals (PGMs) by anion exchange solvent extraction. Industry uses a range of extractants to achieve efficient concentration and separation of PGMs in hydrometallurgical processes, but an understanding of the processes at a molecular level is limited and restricts the options to improve efficiency. The research, sponsored in part by Johnson Matthey and Anglo American, explores two different aspects of the mode of action of reagents used to recover chloride and platinum. Chapter 1 reviews the extraction of chloridometalates in hydrometallurgy and other methods used to recover PGMs. The chapter also covers current ideas on whether formation of outer-sphere anion-cation molecular assemblies or whether larger supramolecular aggregates are responsible for the extraction of PGMs. These two separate routes of study can be investigated by various computational and experimental methods, which are discussed in Chapter 2. In Chapter 3, the model systems chosen to develop the methodologies utilised throughout the thesis are presented. The development involves the extraction of chloride ions by tributyl-phosphate (TBP) and then is extended to extraction of PGM chloridometalates in Chapter 4. Computational methods are used to probe the atomistic and supramolecular theories in predicting the most likely assemblies which will be formed in the transfer of anions between the aqueous and organic phase. Slope analysis and the determination of the contents of the organic phase is used to validate computational models, along with spectroscopic techniques to determine shape and size of assemblies formed during extraction. The application of these methodologies to an amide extractant is discussed in Chapter 5. Computational methods predict the probability of formation of specific complex assemblies during the extraction of PtCl62- by protonated forms of the amide. Determination of the stoichiometry involved in formation of the complex assemblies by slope analysis is reported along with analysis of water, metal and chloride content to confirm the computational model. Final conclusions on all systems explored within the thesis and suggestions for future work are presented in the final chapter. The combination of experimental and computational methods are shown to be very efficient in defining mechanisms of extraction, involving determination of structures formed during the process and how and why they form.
Supervisor: Morrison, Carole ; Love, Jason Sponsor: Engineering and Physical Sciences Research Council (EPSRC)
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: solvent extraction ; metallurgy ; molecular dynamics ; DFT ; chemistry ; platinum