Use this URL to cite or link to this record in EThOS: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.735569 |
![]() |
|||||||
Title: | Structural studies of mid-Z lanthanide elements at high pressure | ||||||
Author: | Husband, Rachel Jane |
ISNI:
0000 0004 6499 6687
|
|||||
Awarding Body: | University of Edinburgh | ||||||
Current Institution: | University of Edinburgh | ||||||
Date of Award: | 2015 | ||||||
Availability of Full Text: |
|
||||||
Abstract: | |||||||
The majority of the metallic elements adopt simple, high-symmetry structures at ambient pressure. These consist of a highly-ordered arrangement of atoms, which can be described by a crystal lattice that is periodic in three dimensions. It may be expected that close-packed structures, such as face-centred cubic (fcc) and hexagonal close-packed (hcp), would be favoured at high pressures due to the increase in density. However, many of these elements transform to lowsymmetry, complex structures on compression. In particular, a number have been observed to adopt incommensurately-modulated structures at high pressure. In these structures, atoms are displaced from their average positions by a modulation wave, the wavelength of which is an irrational multiple of the lattice periodicity. Diamond-anvil cells (DACs) can be used to compress materials to over a million times atmospheric pressure. In these devices, a small sample is compressed between the tips of two diamond anvils. The atomic arrangement of materials at extreme pressures can then be probed using the intense x-ray beams provided by synchrotron sources. In this work, the high-pressure crystal structures of the lanthanide elements europium (Eu) and samarium (Sm) have been investigated using angle-dispersive x-ray powder dffraction techniques. The high-pressure structural behaviour of Eu has been found to be remarkably different from that of the other lanthanide elements. Two new high-pressure phases of Eu are reported, both of which have an incommensurately-modulated crystal structure.
|
|||||||
Supervisor: | McMahon, Malcolm | Sponsor: | Not available | ||||
Qualification Name: | Thesis (Ph.D.) | Qualification Level: | Doctoral | ||||
EThOS ID: | uk.bl.ethos.735569 | DOI: | Not available | ||||
Keywords: | Diamond-anvil cells ; lanthanide elements ; europium ; samarium ; x-ray powder diffraction ; lanthanide elements | ||||||
Share: |