Use this URL to cite or link to this record in EThOS: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.685545 |
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Title: | In-situ and time resolved observation of uranium corrosion applied to nuclear waste storage and disposal | ||||
Author: | Stitt, Camilla Amy de-Maid |
ISNI:
0000 0004 5915 4370
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Awarding Body: | University of Bristol | ||||
Current Institution: | University of Bristol | ||||
Date of Award: | 2015 | ||||
Availability of Full Text: |
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Abstract: | |||||
The presence of uranium in grouted Magnox intermediate level waste (ILW) containers
is a concern for the nuclear waste industry. Recent inspection of 16 randomly
selected ILW containers revealed bulging around the circumference of 3
containers, the cause of which is currently unknown. The bulges are suspected to
be related to the intermittent existence of large uranium masses, the corrosion of
which produces products almost twice the volume of uranium metal. Formation
of hydrogen and uranium hydride through the oxidation of uranium and Magnox
with water is of particular concern owing to their pyrophoric nature on exposure to
oxidising conditions should the container fail. The understanding of uranium corrosion
mechanisms and rates in ILW containment is therefore vital in assessing the
risk posed by the bulging waste containers during container storage, transportation
and disposal. The following study aimed to contribute to this understanding
by performing experiments that transition from laboratory based investigations to
conditions more relevant to real ILW scenarios.
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Supervisor: | Not available | Sponsor: | Not available | ||
Qualification Name: | Thesis (Ph.D.) | Qualification Level: | Doctoral | ||
EThOS ID: | uk.bl.ethos.685545 | DOI: | Not available | ||
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