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Title: Ignition of suspensions of coal and biomass particles in air and oxy-fuel for Carbon Capture and Storage (CCS) and climate change mitigation
Author: Trabadela Robles, Ignacio
ISNI:       0000 0004 5368 8240
Awarding Body: University of Edinburgh
Current Institution: University of Edinburgh
Date of Award: 2015
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Carbon Capture and Storage (CCS) is a legitimate technology option that should be part of a balanced portfolio of mitigation technologies available Post-Kyoto Protocol framework after Paris 2015 and beyond the 2020s or the cost achieving 2 degrees Celsius stabilisation scenario will significantly increase. Oxy-fuel combustion as a CCS technology option increases fuel flexibility. Additionally, oxy-biomass as a bio-energy with CCS (BECCS) technology can achieve negative carbon dioxide (CO2) emissions in sustainable biomass systems. Also, oxygen (O2) production in an air separation unit (ASU) gives potential for extra operational flexibility and energy storage. In this work, new designs of 20 litre spherical (R-20) and 30 litre non-spherical (R-30) ignition chambers have been built at the University of Edinburgh to carry-out dust ignition experiments with different ignition energies for evaluating pulverised fuel ignitability as a function of primary recycle (PR) O2 content for oxy-fuel PF milling safety. A set of coals and biomasses being used (at the time of submitting this work) in the utility pulverised fuel boilers in the UK have been employed. Coal and biomass dusts were ignited in air and oxy-fuel mixtures up to 30 % v/v O2 balance mixture CO2 where peak pressures (Pmax) from ignition were recorded. Pressure ratios (Pmax/Pinitial) were determined the key parameter for positive ignition identification with a value above 2.5 to be considered positive. Particle size effects in coal and biomass ignition were evaluated. Results on biomass were more variable than with coals, requiring a stronger ignition source (5,000 J) mainly due to larger particle sizes. Finer biomass particles behaved similarly to air ignition in 25 % v/v O2 in CO2. Larger particles of biomass did not ignite at all for most cases even reaching 30 % v/v O2 in CO2. A reference coal used, El Cerrejon, behaved as expected with 30 % v/v O2 balance CO2 matching air case; particles between 75-53 microns had lower ignitability than finer below 53 microns but were critical in devolatilisation. Most fuels did not ignite in 21 % v/v in CO2 below 200 g/m3 concentrations. The use of adequate ignition energy strength is needed for the PF mill safety case, with 5,000 J energy required for the biomasses tested. An indication of potential ignition chamber volume and geometry effect has also been observed when comparing results from R-20 and R-30 ignition chambers. Important implications include that oxy-biomass PR with 21 % v/v O2 content would give improved pulverised fuel (PF) milling safety when compared to air firing but reduced ignitability and a 25 % v/v O2 balance CO2 atmosphere would approach to oxy-biomass ignition behaviour in air in mills.
Supervisor: Gibbins, Jon; Chalmers, Hannah Sponsor: Engineering and Physical Sciences Research Council (EPSRC)
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: coal ; biomass ; ignition ; Oxy-fuel ; carbon capture and storage ; CCS