Use this URL to cite or link to this record in EThOS: https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.571814
Title: Electrophoretic deposition of primary coat onto investment casting wax patterns
Author: Roach, Peter J.
ISNI:       0000 0004 2734 0419
Awarding Body: University of Birmingham
Current Institution: University of Birmingham
Date of Award: 2013
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Abstract:
The objective of the work reported in this thesis was to tailor a colloidal processing technique called electrophoretic deposition (EPD) for use within the investment casting shell formation process, where the EPD coating procedure would be used to form the primary ceramic coating on the melt-out substrate. EPD takes place due to the presence of an electric field within the suspension medium, which attracts charged particles in the suspension towards an electrode of opposite charge, onto which they are deposited. For the complex structures created using investment casting, the die cast patterns used as the substrate for the ceramic have to be easily removed, and so substrates materials that can either be melted or dissolved out the material to leave the hollow ceramic shell used. To implement EPD into the investment casting process, this substrate needed to be conducting, and so conducting particle-filled investment casting waxes were created and analysed. Carbon black and graphite filler were incorporated into waxes, and the conductivity and rheology of the resultant composites were studied, to gauge their suitability as an investment casting pattern material. On the basis of both cost and for environmental reasons, the use of aqueous suspension media for EPD was preferred over the more commonly used organic systems. EPD was carried out using zircon in aqueous suspension, and the low particle concentration suspensions were stabilised through pH modification and anionic dispersant addition. The effect of suspension parameters and EPD set-up parameters on the coatings formed on compressed graphite electrodes and conductive wax electrodes were studied, through yield measurements and cross sectional analysis using scanning electron microscopy.
Supervisor: Not available Sponsor: EPSRC
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.571814  DOI: Not available
Keywords: TN Mining engineering. Metallurgy
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