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Title: The solvothermal synthesis of early transition metal fluorides
Author: Aldous, David W.
ISNI:       0000 0004 2716 9391
Awarding Body: University of St Andrews
Current Institution: University of St Andrews
Date of Award: 2008
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In this thesis, 60 crystal structures which have been synthesised by the solvothermal method are reported, with 57 of them representing novel materials. The remaining three materials have previously been reported but have been made by a new and milder method of synthesis. Ti, Zr, Hf, V, Nb, Ta and Mo have all been used to make fluoride or oxyfluoride materials at temperatures ranging from 60C to 200C. Both inorganic and organic moieties ("templates") have been used to direct the formation of the (oxy)fluoride materials, usually as an anionic species. These materials have then been studied for their magnetic properties, where relevant. Initially, 10 vanadium-based compounds were made at 100C using a range of templates. Through variations in water content, temperature and cation ratio, a further 19 compounds were synthesised. The inorganic species in these structures ranged from monomers, to dimers, tetramers and chains, to infinite 2D sheets. A family of vanadium compounds has been synthesised, with piperazine as a template, which shows an increase in covalent connectivity through the increase of the reaction temperature, with a decrease in oxidation state as a result. These materials are also interrelated through the use of a "Y" shaped motif in their structural composition. Through a change in cation content a novel trigonal chain compound (related to the structure of CsCrF₄) has been synthesised with piperazine which possibly shows strong geometric frustration. Vanadium oxyfluoride analogues of (VO)₂P₂O₇ have been made, which show interesting magnetic properties with a range of different templates, ranging from alkali metal cations to the bulky protonated template trans 1,2 bis (4-pyridyl) ethene. The best fits to the magnetic susceptibility data are obtained with an antiferromagnetic Heisenberg chain model. Nine molybdenum-based structures have also been synthesised, with five of the structures being made through changes in the temperature and cation ratio of the reactions. An example of this is the formation of tetrameric units with ammonium, through the condensation of monomers as a result of an increase in the reaction temperature. A further 22 structures have also been made with metals, M = Ti, Zr, Hf, Nb and Ta. These structures have a tendency to form isolated polyhedral units under the conditions studied in this work. Several examples of isolated [MF₆][superscript n-] and [MF₇][superscript n-] monomers are reported and also one example of a trans-connected [TiOF₄]²⁻ infinite chain structure.
Supervisor: Lightfoot, Philip Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: Fluorides ; Magnetic behaviour ; Transition metals ; SHG ; Solvothermal ; Hydrothermal ; QD181.F1A6 ; Fluorides--Synthesis ; Fluorides--Magnetic properties