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Title: Studies concerning partially reduced nitrogen heterocycles
Author: Chhabra, Siri R.
ISNI:       0000 0004 2718 0822
Awarding Body: Loughborough University of Technology
Current Institution: Loughborough University
Date of Award: 1971
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Carbanion rearrangement studies on selected N-acyl-isoquinoline and -quinoline Reissert compounds have shown that alternative intramolecular rearrangements can compete successfully with the normal 1,2-acyl-migration. The observations have been rationalised mechanistically and their potential value in synthesis demonstrated. In particular the formation of a 1-benzoyl-8-hydroxyisoquinoline derivative has been effected from carbanion rearrangement of the corresponding 8-benzoyloxy Reissert compound. N-Crotonoylisoquinoline Reissert compound carbanion and analogous structures have been shown to undergo a complex reaction in which Michael type attack competes with the normal migration.
Supervisor: Not available Sponsor: Loughborough University of Technology
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available