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Title: Dipyrrin complexes and their uses as self assembling materials
Author: Benstead, Michael
ISNI:       0000 0004 2705 9117
Awarding Body: University of Hull
Current Institution: University of Hull
Date of Award: 2010
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Several series of BODIPYs bearing mesogenic substituents were synthesised and their fluorescence and liquid crystal properties were characterized. Each compound prepared consisted of one BODIPY fluorophore and one, two or three mesogenic units based primarily on a cyanobiphenyl core. Initially, the mesogens were attached to the pyrrolic positions of the fluorophore, but it was found that mesogen attachment at the BODIPY 8-phenyl ring gave an increased preference for mesophase formation due to the molecules having a more rod-like‘ (calamitic) shape. For several of the compounds, a monotropic nematic phase was exhibited, however, no layered phase (e.g. smectic) was observed. Several linker groups between the mesogenic unit and the fluorophore were investigated and it was found that linear linker groups (e.g. ethynyl) had a greater preference for liquid crystal phase formation when compared to non-linear linker groups (e.g. triazole). Two series of di-mesogenic compounds were prepared and a significant stabilisation of the nematic phase was observed when compared to the mono-mesogenic analogues. The compounds bearing the mesogenic units on the 8-phenyl ring were prepared by metal-catalyzed couplings and each series consisted of three compounds with increasing alkyl substitution on the bipyrrolic core of the BODIPY. This resulted in a progressive increase in fluorescence quantum yield of the compounds in each series due to increased rotational restriction of the 8-phenyl ring along with a concurrent decrease in nematic phase stability. This permitted the observation of a structure-property relationship between nematic phase stability and fluorescence intensity. A BODIPY with significantly red-shifted fluorescence was also prepared and three mesogenic units were attached to this compound. Temperature dependant fluorescence measurements were taken in order to observe any relationship between fluorescence and degree of molecular ordering (e.g. nematic phase fluorescence compared to isotropic liquid fluorescence) and several of the compounds were dissolved in a commercial nematic liquid crystal and incorporated into a twisted nematic cell in order to observe the affect that molecular alignment (induced by an electric field) had on the fluorescence.
Supervisor: Boyle, Ross ; Mehl, Georg Sponsor: Not available
Qualification Name: Not available Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: Chemistry