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Title: Metal-based approaches to C(1)-substituted glycals
Author: Wang, Junwei
ISNI:       0000 0004 2677 3810
Awarding Body: University of Bristol
Current Institution: University of Bristol
Date of Award: 2009
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A new metal-based method to synthesize C(1)-substituted glycals has been developed. Starting with the obtained substituted C-glycals, the possibility of a stereocontrolled addition (via azidoselenation) to form β-C-substituted-2-aminoglycosides has been investigated. Instead of forming the expected C-glycosyl derivatives of 2-amino sugars, an inseparable mixture of diastereomers, which were derived from the corresponding C(1)-allylated glycals, has been obtained.
Supervisor: Not available Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available