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Title: A study of the co-ordination behaviour of the chalcogenocyanate ions
Author: Anderson, S. J.
ISNI:       0000 0001 3423 3919
Awarding Body: Loughborough University of Technology
Current Institution: Loughborough University
Date of Award: 1974
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The coordination behaviour of the pseudohalide ions (NCO ̄ NCS ̄ NCSe ̄ NCTe ̄) has been studied. A number of N- and S-bonded thiocyanate complexes of rhodium(I), of the type Rh(PPh3)2(L)CNS (L = ligand), have been prepared. The mode of linkage of the thiocyanate group has been established by means of infrared spectral measurements. The preparation of Rh(PPh3)2(piperidine)NCS clearly demonstrates that a strongly π-accepting ligand such as CO is not a prerequisite for a N-thiocyanato complex of the type Rh(PPh3)2(L)NCS.
Supervisor: Not available Sponsor: Science Research Council
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available