Use this URL to cite or link to this record in EThOS: https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.447881
Title: A study of the co-ordination behaviour of the chalcogenocyanate ions
Author: Anderson, S. J.
ISNI:       0000 0001 3423 3919
Awarding Body: Loughborough University of Technology
Current Institution: Loughborough University
Date of Award: 1974
Availability of Full Text:
Access from EThOS:
Access from Institution:
Abstract:
The coordination behaviour of the pseudohalide ions (NCO ̄ NCS ̄ NCSe ̄ NCTe ̄) has been studied. A number of N- and S-bonded thiocyanate complexes of rhodium(I), of the type Rh(PPh3)2(L)CNS (L = ligand), have been prepared. The mode of linkage of the thiocyanate group has been established by means of infrared spectral measurements. The preparation of Rh(PPh3)2(piperidine)NCS clearly demonstrates that a strongly π-accepting ligand such as CO is not a prerequisite for a N-thiocyanato complex of the type Rh(PPh3)2(L)NCS.
Supervisor: Not available Sponsor: Science Research Council
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.447881  DOI: Not available
Share: