| Use this URL to cite or link to this record in EThOS: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.355548 |
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| Title: | Aspects of the chemistry of iron-nitrosyls | ||||||
| Author: | Hyde, Andrew Richard |
ISNI:
0000 0001 3585 6595
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| Awarding Body: | University of St Andrews | ||||||
| Current Institution: | University of St Andrews | ||||||
| Date of Award: | 1985 | ||||||
| Availability of Full Text: |
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| Abstract: | |||||||
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The work described in this thesis is a study of iron-sulphur-nitrosyls and related compounds. Chapter One is an introduction to the work presented. Chapter one is introduction to the work presented. Chapter Two is concerned with the analogous Fe2(SR)2(CO)6 and its conversion to Fe2(SR)2(NO)4. Chapter Three is concerned with an n.m.r. study of Fe2(SR)2(NO)4, Fe2X4(NO)4 and [Fe4X3(NO)7] (X=S, Se). Chapter four is concerned with an e.p.r. examination with an n.m.r. study of Fe2(SR)2(NO)4, Fe2X4(NO)4 [Fe4X3(NO)7] (X=S,Se). Chapter four is concerned with an e.p.r. examination of Fe2(SR)2(NO)4 and bridging ligand exchange reactions. Chapter Five is concerned with a similar examination of Fe2I2(NO)4.Chapter six is concerned with an examination of ligand exchange processes in Fe4S4(NO)4 and [Fe4S4(NO)4]. Chapter Seven is concerned with an investigation of iron-sulphur protein models and their conversion to iron-nitrosyls.
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| Supervisor: | Glidewell, Christopher | Sponsor: | Cancer Research Campaign | ||||
| Qualification Name: | Thesis (Ph.D.) | Qualification Level: | Doctoral | ||||
| EThOS ID: | uk.bl.ethos.355548 | DOI: | Not available | ||||
| Keywords: | QD305.N8H9 ; Nitro compounds | ||||||
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