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Title: Lead, indium and tin complexes of Schiff bases derived from salicylaldehydes
Author: Ross, Andrew Thomas
ISNI:       0000 0001 3537 1221
Awarding Body: Loughborough University
Current Institution: Loughborough University
Date of Award: 1998
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A number of lead(II) complexes prepared from the reactions of various disalicylaldimines with lead(II) salts have been characterised spectroscopically, and in two cases have been analysed by X-ray diffraction. The reaction of N,N'-bis(salicylidene)ethane-1,2-diamine (H2salen) with Pb(ClO4)2·6H2O produced a novel complex [Pb3(salen)2][ClO4]2 in which the ligand bonds to the lead in two different modes. The interaction of N,N'-bis(3-methoxy-salicylidene)ethane-1,2-diamine with Pb(ClO4)2·6H2O yielded a mononuclear complex wherein the ligand bonds to the lead(II) atoms only through its phenolic oxygens.
Supervisor: Not available Sponsor: EPSRC
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: Inorganic chemistry