| Use this URL to cite or link to this record in EThOS: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.279934 |
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| Title: | Synthetic and mechanistic investigations of organoplatinum chemistry | ||||||
| Author: | Phillips, Ian G. |
ISNI:
0000 0001 3488 3452
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| Awarding Body: | University of Glasgow | ||||||
| Current Institution: | University of Glasgow | ||||||
| Date of Award: | 1981 | ||||||
| Availability of Full Text: |
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| Abstract: | |||||||
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The addition of PMe2Ph to [ Pt2Cl4(PMe2Ph)2] at low temperatures produces the ions [PtCl (PMe2Ph)3]+ and [PtCl3(PMe3Ph)]- as major products, as well as some of the expected [PtCl2(PMe2Ph)2]. Less ionic material is produced from the addition of PBu3 to [Pt2Cl4(PMe2Ph)2] and PMe2Ph to [Pt2Cl4(PBu3)3] , and none at all from the addition of PBu3 to [Pt2Cl4(PBu3)2] . Ionic materials are also produced in the reactions of PMePh2 and SPMePh2 with [Pt2Cl4(PBu3)2] , and of PBu3 and SPBu3 with [Pt2Cl4(PMePh2)2]. The nature of the neutral ligands involved has a profound effect on the course of the reactions.
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| Supervisor: | Not available | Sponsor: | Not available | ||||
| Qualification Name: | Thesis (Ph.D.) | Qualification Level: | Doctoral | ||||
| EThOS ID: | uk.bl.ethos.279934 | DOI: | Not available | ||||
| Keywords: | Organic chemistry | ||||||
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