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Title: Synthetic and mechanistic investigations of organoplatinum chemistry
Author: Phillips, Ian G.
ISNI:       0000 0001 3488 3452
Awarding Body: University of Glasgow
Current Institution: University of Glasgow
Date of Award: 1981
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The addition of PMe2Ph to [ Pt2Cl4(PMe2Ph)2] at low temperatures produces the ions [PtCl (PMe2Ph)3]+ and [PtCl3(PMe3Ph)]- as major products, as well as some of the expected [PtCl2(PMe2Ph)2]. Less ionic material is produced from the addition of PBu3 to [Pt2Cl4(PMe2Ph)2] and PMe2Ph to [Pt2Cl4(PBu3)3] , and none at all from the addition of PBu3 to [Pt2Cl4(PBu3)2] . Ionic materials are also produced in the reactions of PMePh2 and SPMePh2 with [Pt2Cl4(PBu3)2] , and of PBu3 and SPBu3 with [Pt2Cl4(PMePh2)2]. The nature of the neutral ligands involved has a profound effect on the course of the reactions.
Supervisor: Not available Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: Organic chemistry