Use this URL to cite or link to this record in EThOS: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263623 |
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Title: | Organo-sulfur phosphorus chemistry | ||||||
Author: | Foreman, Mark Russell StJohn |
ISNI:
0000 0001 3474 6319
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Awarding Body: | Loughborough University | ||||||
Current Institution: | Loughborough University | ||||||
Date of Award: | 1998 | ||||||
Availability of Full Text: |
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Abstract: | |||||||
P-organo-substituted dithiadiphosphetane disulfides have been prepared by the reaction of ferrocene and arenes with P4S10. Reaction of these compounds and Lawesson's reagent with alkenes, 2,3-dimethylbutadiene and other compounds gave organo-sulfur phosphorus compounds including 1,2-thiaphosphetane-2-sulfides such as P-ferrocenyl 1,2,5,5,7,8-hexamethyltricyclo[3,2,5,2,0]-3-thia-4-phospho-oct-7-ene-4-sulfide and a thiaphosphorine sulfide (P-ferrocenyl 4,5-dimethyl-3H,6H-1,2-thiaphosphinine-2-sulfide). Treatment of P-ferrocenyl thiaphosphorine sulfide with BuLi followed by carbon containing electrophiles (such as benzyl bromide or 2,4-dinitrochlorobenzene) gave ring-opened products. In addition treatment of dithiadiphosphetane disulfides with organic carbonyl compounds, including ketones, gave thiocarbonyl compounds. Platinum complexes were formed from the dithiadiphosphetane disulfides.
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Supervisor: | Not available | Sponsor: | Not available | ||||
Qualification Name: | Thesis (Ph.D.) | Qualification Level: | Doctoral | ||||
EThOS ID: | uk.bl.ethos.263623 | DOI: | Not available | ||||
Keywords: | Dithiadiphosphetane disulfides | ||||||
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