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Title: o-Nitrosophenol complexes and their synthetic potential
Author: Kensett, Malcolm James
ISNI:       0000 0001 3597 3767
Awarding Body: Polytechnic of North London
Current Institution: London Metropolitan University
Date of Award: 1980
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Interaction of triphenylphosphine with Ni(XqO)2 (XqOH = 2-nitrosophenol, X = 4-chloro, 4-bromo, 4-methyl and 5-methoxy) resulted in deoxygenation to give mainly bis(2-triphenylphosphiniminophenolato) nickel(ll), Similarly the interaction of triphenyl phosphine with Zn(qO)2 (qOH = 5-methoxy-2- nitrosophenol) involved deoxygenation and formation of bis(2-triphenylphosphiniminophenolato)zinc(ll). Action of dilute hydrochloric acid on these complexes afforded the hydrochlorides of the corresponding N(2-hydroxybenzene)iminotriphenyl phosphoranes. The hydrochlorides on neutralisation with sodium carbonate gave, in most cases, the parent N(2-hydroxybenzene)- iminotriphenyl phosphorene.
Supervisor: Not available Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: 540 Chemistry & allied sciences