Use this URL to cite or link to this record in EThOS: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.259221 |
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Title: | o-Nitrosophenol complexes and their synthetic potential | ||||||
Author: | Kensett, Malcolm James |
ISNI:
0000 0001 3597 3767
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Awarding Body: | Polytechnic of North London | ||||||
Current Institution: | London Metropolitan University | ||||||
Date of Award: | 1980 | ||||||
Availability of Full Text: |
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Abstract: | |||||||
Interaction of triphenylphosphine with Ni(XqO)2 (XqOH = 2-nitrosophenol, X = 4-chloro, 4-bromo, 4-methyl and 5-methoxy) resulted in deoxygenation to give mainly bis(2-triphenylphosphiniminophenolato) nickel(ll), Similarly the interaction of triphenyl phosphine with Zn(qO)2 (qOH = 5-methoxy-2- nitrosophenol) involved deoxygenation and formation of bis(2-triphenylphosphiniminophenolato)zinc(ll). Action of dilute hydrochloric acid on these complexes afforded the hydrochlorides of the corresponding N(2-hydroxybenzene)iminotriphenyl phosphoranes. The hydrochlorides on neutralisation with sodium carbonate gave, in most cases, the parent N(2-hydroxybenzene)- iminotriphenyl phosphorene.
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Supervisor: | Not available | Sponsor: | Not available | ||||
Qualification Name: | Thesis (Ph.D.) | Qualification Level: | Doctoral | ||||
EThOS ID: | uk.bl.ethos.259221 | DOI: | Not available | ||||
Keywords: | 540 Chemistry & allied sciences | ||||||
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