Use this URL to cite or link to this record in EThOS: https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.256032
Title: Properties of mixed acid relevant to nitration
Author: Field, John P.
ISNI:       0000 0001 3463 7059
Awarding Body: Loughborough University of Technology
Current Institution: Loughborough University
Date of Award: 1980
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Abstract:
In the first part contours of the second order rate constant (k2) for homogeneous aromatic nitration have been determined over a portion of the three-component diagram (H2SO4-HNO3-H2O) using three aromatics of differing reactivity (toluene, chlorobenzene and p-dichlorobenzene). Activation energy measurements are also reported over the same section of the three-component diagram. Those results lead to the conclusion that the major factor in rate and energy considerations is the acidity of the medium and that some rates previously measured in heterogeneous systems are kinetically controlled.
Supervisor: Not available Sponsor: Science Research Council
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.256032  DOI: Not available
Keywords: Chemistry, general
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