Use this URL to cite or link to this record in EThOS: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.254088 |
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Title: | Experimental and theoretical studies of molecular transition moments | ||||||
Author: | Chalkley, Stephen Wilfred |
ISNI:
0000 0001 3526 1030
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Awarding Body: | University of Southampton | ||||||
Current Institution: | University of Southampton | ||||||
Date of Award: | 1980 | ||||||
Availability of Full Text: |
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Abstract: | |||||||
Firstly, Stark effects have been observed for individual lines in the excitation spectrum of the NHD radical, recorded in the visible region with a tunable dye laser. Individual MT components have been resolved with Doppler limited resolution. The results are interpreted in terms of an interaction between the applied electric field and a ground state dipole moment determined to be 1.82±.05D'and a dipole moment in the (0,9,0) level of the A'A' state determined to be 0.19±.06D. Secondly, a simple perturbation treatment is used to reduce the number of independent transition moments (which may, in principle, be many) necessary to describe the intensity distribution of intercombination transitions (involving AS=l) in diatomic molecules. It is demonstrated that, in general, the number of independent transition moments can always be reduced to three (four for if - II transitions). The treatment is valid for weak spin-orbit interaction between electronic states, and yields formulae, by which any intercombination transition moment can be expressed in terms of one of three parameters - u//, ull,or h12. Several examples of the application of these formulae is given.
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Supervisor: | Not available | Sponsor: | Not available | ||||
Qualification Name: | Thesis (Ph.D.) | Qualification Level: | Doctoral | ||||
EThOS ID: | uk.bl.ethos.254088 | DOI: | Not available | ||||
Keywords: | Atomic physics & molecular physics | ||||||
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