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Title: Preparation, redox and substitution reactions of solvated metal ions in non aqueous media
Author: Cameron, James Hay
ISNI:       0000 0001 3515 0402
Awarding Body: University of Glasgow
Current Institution: University of Glasgow
Date of Award: 1980
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Solvated iron(II), in MeCN solution, is prepared by oxidation of iron metal with WF6 , NOPF6 and PF5 or by fluoride ion transfer from FeF2 to PF5 or AsF5. Fe(NCMe)6 3+ is not produced from oxidation of iron metal, fluoride ion transfer from FeF3 or oxidation of Fe(NCMe)6 2+. Fe(NCMe)6 2+ is oxidised, by Cl2 producing FeCl4-. A ligand is necessary to stabilise Fe(lll) in MeCN.
Supervisor: Not available Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: Chemistry, general