| Use this URL to cite or link to this record in EThOS: | https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.253238 |
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| Title: | Preparation, redox and substitution reactions of solvated metal ions in non aqueous media | ||||||
| Author: | Cameron, James Hay |
ISNI:
0000 0001 3515 0402
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| Awarding Body: | University of Glasgow | ||||||
| Current Institution: | University of Glasgow | ||||||
| Date of Award: | 1980 | ||||||
| Availability of Full Text: |
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| Abstract: | |||||||
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Solvated iron(II), in MeCN solution, is prepared by oxidation of iron metal with WF6 , NOPF6 and PF5 or by fluoride ion transfer from FeF2 to PF5 or AsF5. Fe(NCMe)6 3+ is not produced from oxidation of iron metal, fluoride ion transfer from FeF3 or oxidation of Fe(NCMe)6 2+. Fe(NCMe)6 2+ is oxidised, by Cl2 producing FeCl4-. A ligand is necessary to stabilise Fe(lll) in MeCN.
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| Supervisor: | Not available | Sponsor: | Not available | ||||
| Qualification Name: | Thesis (Ph.D.) | Qualification Level: | Doctoral | ||||
| EThOS ID: | uk.bl.ethos.253238 | DOI: | Not available | ||||
| Keywords: | Chemistry, general | ||||||
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