Use this URL to cite or link to this record in EThOS: http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.714330
Title: Gas permeability of gas diffusion media used in polymer electrolyte fuel cells
Author: Orogbemi, Olutomisin Manase
ISNI:       0000 0004 6347 8191
Awarding Body: University of Sheffield
Current Institution: University of Sheffield
Date of Award: 2017
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Abstract:
The awareness of global climate change by emissions of greenhouse gases from fossil fuel combustion is widely known by current society. Polymer Electrolyte Fuel cell (PEFC) technology has been a very promising clean technology with high efficiency that has been used in a wide range of portable, automotive and stationary applications. The fuel cell research has been developing very rapidly and successfully in the last few years. However, some issues remain largely unresolved, namely water management and high cost of the PEFC component. One of the efficient and cost-effective ways to improve the design of the PEFC and consequently resolve the above mentioned issues is through modelling. However, the built PEFC models need to be fed with accurate transport coefficients to enhance their productivity. One of the most important transport coefficients is the gas permeability of the PEFC porous media which highly affects the convective flow. Therefore, in this thesis, thorough experimental studies have been conducted to investigate the gas permeability of gas diffusion media used in PEFCs. The focus has been on the effects of the following on the gas permeability of the gas diffusion layers (GDLs): (i) type of carbon black used in the microporous layers (MPL) attached to the GDL, (ii) carbon and polytetrafluoroethylene (PTFE) loading, and (iii) the thickness of the MPL. Further, a novel method has been proposed to estimate the penetration of the MPL into the carbon substrate (i.e. the GDL before being coated with the MPL ink). Also, the effect of sintering on the gas permeability of the MPL has been investigated for the first time.
Supervisor: Pourkashanian, Mohamed ; Lin, Ma ; Hughes, Kevin ; Ingham, Derek Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.714330  DOI: Not available
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