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Title: Asymmetric synthesis of homoallylic alcohols and their applications
Author: Barlog, Maciej L.
Awarding Body: University of Glasgow
Current Institution: University of Glasgow
Date of Award: 2011
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Herein it is presented a further development of the well-established catalytic asymmetric allylation of aldehydes leading to enantiopure homoallylic alcohols Stereogenic centre(s) served as the foundation for synthesis of a variety of other advanced intermediates and building blocks with multiple chiral centres - New approaches to homoallylic alcohols were dementrated with excellent control of chiral centers - Biologically relevant carbohydrate analogues were synthesised in four possible configurations using singlet oxygen raction as the key step - δ-hydroxy-β-amino acids were synthetised diastereoselectively using Pd catalysis as the key step. - A novel approach to synthesis of isoxazolidines and pyrazolidines was demonstrated.
Supervisor: Not available Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: QD Chemistry