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Title: Subduction zone processes and continental crust formation in the southern Central Andes : insights from geochemistry and geochronology
Author: Jones, Rosemary Ellen
ISNI:       0000 0004 5353 572X
Awarding Body: University of Edinburgh
Current Institution: University of Edinburgh
Date of Award: 2014
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Subduction zones, such as the Andean convergent margin, are the sites at which new continental crust is generated, and where subducting material is either recycled to the crust via arc magmatism or transferred to the deep mantle. The composition of arc magmas and associated new continental crust reflects variable contributions from mantle, crustal and subducted reservoirs. Insights into crustal growth and recycling processes in the southern Central Andes, specifically in the Pampean flat-slab segment, have been gained by utilising a range of petrological, geochronological and geochemical techniques. These techniques have been applied to a suite of Late Cretaceous (~73 Ma) to Late Miocene (~6 Ma) intrusive (granitoids) and extrusive (basalts to rhyolites) arc rocks collected from an east - west transect across the Andean Cordillera. The oxygen and hafnium isotopic composition of the accessory mineral zircon allows mantle-derived melts contaminated with older, upper continental crustal to be identified. Boron isotopic compositions of melt inclusions, combined with concentrations of certain incompatible trace elements, can be used to assess the source and influence of fluids derived from subducting material on the melt source region. The southern Central Andes provides a particularly interesting area to study these processes as the thickness of the continental crust has increased significantly over the course of the Cenozoic (from ~35 km to >50 km) and the angle of the subducting Nazca plate has shallowed since ~18 Ma, causing the position of the volcanic arc to migrate to the east. In order to unravel the complexities involved with constraining the contributions to arc magmas at an active continental margin, a range of geochronological, geochemical, and geothermobarometric techniques, including high resolution, micro-analysis of mineral phases and melt inclusions, have been applied. High resolution, U-Pb dating of magmatic zircon has improved regional stratigraphy in the Pampean flat-slab segment (between ~29 and 32 °S) and provided an accurate temporal constraint for geochemical and geothermobarometric data. The results of in-situ O and Lu-Hf isotope analysis of zircon show both distinct temporal and spatial variations across the Andean arc. The observed isotopic variability is attributed to variable contamination of mantle-derived melts with distinct Andean basement terranes, which vary east – west in composition and age. ‘Mantle-like’ δ18O(zircon) values, juvenile initial ƐHf(zircon) values and a lack of inherited, xenocrystic zircon cores, suggests the Late Cretaceous (~73 Ma) to Eocene (~39 Ma) plutons located in the Principal Cordillera of Chile, experienced very little interaction with the upper continental crust. Amphibole – plagioclase geothermobarometry indicates these calc-alkaline granitoids, which form extensive north – south trending belts, were emplaced at shallow depths in the crust (~4 – 5 km). Therefore the Late Cretaceous to Late Eocene is interpreted as a period of significant upper crustal growth. The isotopic variability in the Late Oligocene (~26 Ma) to Late Miocene (~6 Ma) arc magmatic rocks demonstrates that during thickening of the continental crust and migration of the Andean arc to the east, arc magmas assimilated Late Paleozoic to Early Mesozoic basement. In addition, arc magmas erupted/emplaced in the Argentinean Precordillera (i.e. farthest east from the trench) assimilated a Grenville-aged (~ 1330 – 1030 Ma) basement. The youngest arc magmas (~6 Ma) erupted in the Frontal Cordillera also show evidence for the assimilation of this ancient basement terrane, potentially signalling under-thrusting beneath the Frontal Cordillera. Overall, the later part of the Cenozoic represents a period of crustal reworking. Boron concentrations and isotope ratios measured in pyroxene hosted melt inclusions and for the first time in zircon hosted melt inclusions, are higher than the values expected for the mantle wedge and show significant variations with time. The source of the Paleocene (~61 Ma) arc magmas were influenced by fluids primarily derived from altered oceanic crust. Lower δ11B values and boron concentrations obtained for Oligocene (25 – 23 Ma) arc magmatic rocks reflects a diminished influence of slab-derived fluids reflecting a greater depth to the top of the slab. Fluids derived from serpentinite influenced the source of the arc magmas after ~19.5 Ma. This has been linked with the intersection of the Juan Fernández Ridge, a volcanic seamount chain associated with hydrated and serpentinised oceanic lithosphere.
Supervisor: Kirstein, Linda Sponsor: Natural Environment Research Council (NERC)
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID:  DOI: Not available
Keywords: subduction ; arc magmatism ; southern Central Andes ; zircon ; geochemistry ; boron isotopes