Use this URL to cite or link to this record in EThOS: http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.603089
Title: The chemistry of new cyclic phosphorus(III) ligands
Author: Ekubo, Allen T.
Awarding Body: Loughborough University
Current Institution: Loughborough University
Date of Award: 2009
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Abstract:
A range of new aniline derivatives of tetrakis(hydroxymethyl)phosphonium chloride represented as [P(CH2NHR)4]Cl, where R = phenyl or a substituted phenyl group were synthesised by reacting tetrakis(hydroxymethyl)phosphonium chloride with different aniline precursors in EtOH. Similarly, new phenylenediamine derivatives of tetrakis(hydroxymethyl)phosphonium chloride [P{(CH2NHhRh]Cl, [R = C614, C6H3Me, C6H3COPh, C6H2C414] were synthesised by reacting tetrakis(hydroxymethyl)phosphonium chloride with phenylenediamine precursors. Selected aniline derivatives of tetrakis(hydroxymethyl)phosphonium chloride were reacted with triethylamine in acetone at room temperature to give the corresponding diazaphosphorinane ligands cyclo- {CH2N(R)CH2N(R)CH2-P}-CH2N(H)R , where R = phenyl or a substituted phenyl group. Some of the diazaphosphorinane ligands were reacted with Ru(II), Rh(III), Ir(III) , Pd(lI) and Pt(lI) precursors to form new transition metal complexes.
Supervisor: Not available Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.603089  DOI: Not available
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