Use this URL to cite or link to this record in EThOS: http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.571491
Title: An investigation of molecular opacities for late-type stars
Author: Sharp, Christopher Martin
Awarding Body: University of St Andrews
Current Institution: University of St Andrews
Date of Award: 1981
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Abstract:
This work investigates molecular opacities under conditions appropriate to the atmospheres of late-type stars. Given a specified initial abundance of the chemical elements, the equations of atomic ionization and molecular dissociation are solved by iteration for various temperatures and densities. With the abundances of the atomic and molecular species so determined at a particular temperature and density, the continuous absorption coefficient due to a number of processes is first computed, then the molecular band absorption coefficient is computed line-by-line superimposed for diatomic and triatomic molecules considered separately. The band calculations for the diatomic molecules include all possible isotopic variants, but computing resources did not permit this degree of detail for triatomic molecules, nor diatomic and triatomic molecules to be considered together. These calculations are performed for a number of different temperatures and densities. The theory for calculating the spectral lines due to molecules is discussed in some detail, with various methods being investigated for computing opacities including the contributions from these spectral lines. With the computing resources available, the best method for the calculation of the opacity due to the molecular absorption is found to be that of opacity sampling, sampling is adequate, provided the frequency of sampling is adequate. From the results presented in this thesis, a number of important conclusions can be drawn. At low temperatures and high densities, pressure-induced absorption due to molecular hydrogen is an important source of continuous opacity. Isotopic variants of at least diatomic molecules pave to be considered in any calculations, as they can significantly affect the contribution that diatomic molecules make to the Rosseland mean opacities. Also at low temperatures, water is a major source of absorption. Finally, tables of some thermodynamic quantities for the molecular gas are given for a number of temperatures and densities.
Supervisor: Carson, Thomas Richard Sponsor: Science and Engineering Research Council (SERC)
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.571491  DOI: Not available
Keywords: QB809.S5 ; Stars--Atmospheres
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