Use this URL to cite or link to this record in EThOS: http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.562075
Title: Investigating the kinetics and structural effects of azo dye photochemistry using NMR with in situ laser irradiation and ab initio (DFT) calculations
Author: Gibson, David
Awarding Body: University of Edinburgh
Current Institution: University of Edinburgh
Date of Award: 2007
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Abstract:
Reversible cis-trans isomerisation of a series of commercially interesting yellow azo dyes has been studied using the technique of Nuclear Magnetic Resonance (NMR) spectroscopy with in situ laser irradiation. Photostationary state (PSS) spectra of the azo dyes, provided by coupling laser irradiation into the sample within the probe of the NMR spectrometer, have allowed observation of azo cis isomer species that would otherwise elude detection and characterisation by NMR due to their rapid thermal decay times. The NMR results have been combined with geometry optimised structures obtained through ab initio (DFT) calculations in order to allow visualisation of the trans and cis isomer species, and explain NMR spectral features. In the majority of cases, these in vacuo calculated structures show a great deal of correlation with NMR observations of asymmetric, cis-trans isomerisation-induced chemical shift changes for protons adjacent to the azo bond. The cis isomer spectral pattern for substituted naphthyl group protons can hence be used as a diagnostic tool in determining the correct cis isomer conformation in molecules where more than one conformation may exist. In addition to the aforementioned characterisation studies, in situ irradiation has provided the opportunity to undertake a thorough investigation of the kinetics of photoand thermal isomerisation for the same yellow dye series. The results of these studies have been combined with previous work on similar systems to provide an extensive data set, and conduct analysis in a systematic fashion. Adding fibre-reactive groups, varying phenyl and chlorotriazine ring substituents, and altering naphthyl group sulfonation patterns have a profound effect on both the photochemical and thermal rates of isomerisation in these systems. In certain cases, the same structural calculations noted earlier have proved useful in rationalising the identified kinetic differences. The presence of phenyl substituents ortho to the azo bond has been shown to increase the rate of thermal cis isomer decay. Additionally, substituents bonded to a fibrereactive group distant from the azo bond have an appreciable effect on the barrier to thermal cis-trans isomerisation, but little effect on the photochemical characteristics of each isomer. Several sulfonated naphthyl group patterns have been studied, leading to an observation that sulfonate groups positioned ortho to the azo bond assist in retarding thermal isomerisation, with sulfonate groups in other positions having a much smaller effect. One particular molecule, a component of a currently available commercial dye, was studied for its interesting and previously unexplained behaviour, both photochemical and chemical. The dye demonstrated photoisomerisation at low concentrations only, with aggregation preventing formation of the cis isomer at higher concentrations. The trans isomer was found to undergo degradation to a product which did not photoisomerise. This product was identified as a benzotriazinium compound by multinuclear 2D correlation NMR spectroscopy, formed by a reversible cyclisation reaction involving the azo bond.
Supervisor: Jones, Anita. Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.562075  DOI: Not available
Keywords: Physical Chemistry ; Nuclear Magnetic Resonance ; Photostationary state spectra
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