Use this URL to cite or link to this record in EThOS: http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.470220
Title: Aspects of the coordination chemistry of phosphorus(V) chloro-compounds
Author: Reeve, R. N.
Awarding Body: Durham University
Current Institution: Durham University
Date of Award: 1975
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Abstract:
Acceptor properties of several phosphorus(v) chloro compounds have been studied by solution and solid state (^31)P n.m.r. techniques, using pyridine, 1,10-phenanthroline, 2,2'-dipyridyl and chloride ions as ligands. Six co-ordinate adduct formation has been detected in most systems. As reported previously(^1), phosphorus pentachloride forms a molecular 1:1 adduct with pyridine. Bidentate pyridines produce PC1(_4)(L-L)(^+) PC1(_6)(^-) (L-L = 2,2'-dipyridyl or 1,10-phenanthroline). Non-stoichiometric adducts PC1(_4)phen(+)(PC1(_6)(^-))(_1-x)C1(^-)(_x) (x
Supervisor: Not available Sponsor: Not available
Qualification Name: Thesis (Ph.D.) Qualification Level: Doctoral
EThOS ID: uk.bl.ethos.470220  DOI: Not available
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